It's unlikely that it was originally three rail, unless the body has been changed at some point, as the three rail version was the City of Liverpool and the two rail one the City of London. If I recall correctly, in the two rail version, one wire goes through the hole in the chassis block between the centre wheels to the wire pickup to the insulated wheels, and the other was screwed into the chassis block, which was live to the uninsulated wheels.
I'm afraid that the examples I have had their two rail pickup assemblies removed and replaced with three rail ones, so I can't go and take a body off one to check how the thing is wired up (and, if you're wondering why I didn't just buy a City of Liverpool in the first place, they are one of the Dublo rarities, and attract high prices; a City of London, by comparison, is relatively inexpensive).